(Acetato-κO)(2-{[2-(dimethylamino)ethylimino](phenyl)methyl}-5-methoxyphenolato-κ3 N,N′,O 1)copper(II)
نویسندگان
چکیده
The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu-O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu-O distance in other crystal structures.
منابع مشابه
(2,2′-Bipyridine)(2-{1-[2-(dimethylamino)ethylimino]ethyl}-4-methoxyphenolato)copper(II) perchlorate
The Cu atom of the title complex, [Cu(C(13)H(19)N(2)O(2))(C(10)H(8)N(2))]ClO(4), has a distorted square-pyramidal geometry with all three of the donor atoms from the N,N',O-tridentate Schiff base ligand in the equatorial positions and the bipyridine N atoms in an equatorial-axial binding mode. The Cu atom is 0.1801 (11) Å above the N(3)O mean basal plane.
متن کاملBis(μ2-quinoline-2-carboxylato)-κ3 N,O 1:O 1;κ3 O 1:N,O 1-bis[(acetato-κO)(ethanol-κO)lead(II)]
In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl-ate group of the quinoline-2-carboxyl-ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa-hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter-actions distort the geometry toward...
متن کاملBis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato-κ3 N,N′,O 1}nickel(II)
The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.
متن کاملcatena-Poly[[tetrakis(μ2-acetato-κ2 O:O′)dicopper(II)(Cu—Cu)]-μ2-acetato-κ2 O:O′-[bis[μ2-3-(dimethylamino)propan-1-olato]-κ2 N,O:O;κ2 O:N,O-bis[(tetrahydrofuran-κO)copper(II)]]-μ2-acetato-κ2 O:O′]
The title complex, [Cu(4)(C(5)H(12)NO)(2)(C(2)H(3)O(2))(6)(C(4)H(8)O)(2)](n), consists of dinuclear [Cu(2)(C(5)H(12)NO)(2)(THF)(2)] (THF is tetra-hydro-furan) and [Cu(2)(CH(3)COO)(4)] units linked through acetate ions, generating parallel one-dimensional polymeric chains propagating in the [10] direction. In the first dinuclear unit, Cu(II) ions related by inversion symmetry are bridged by two ...
متن کاملcatena-Poly[[(2-{1-[2-(2-aminoethylamino)ethylimino]ethyl}-5-methoxyphenolato-κ4 N,N′,N′′,O)copper(II)]-μ-nitrato-κ2 O:O′]
In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol-ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu-O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa-hedral coordinati...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008